Sahih al-Bukhari, Volume 4, Book 52, Hadith 189 (USC-MSA) ⓘ
Narrated Anas: When the Prophet intended to write a letter to the ruler of the Byzantines, he was told that those people did not read any letter unless it was stamped with a seal. So, the Prophet got a silver ring-- as if I were just looking at its white glitter on his hand ---- and stamped on it the expression "Muhammad, Apostle of Allah".
حَدَّثَنَا عَلِيُّ بْنُ الْجَعْدِ، أَخْبَرَنَا شُعْبَةُ، عَنْ قَتَادَةَ، قَالَ سَمِعْتُ أَنَسًا ـ رضى الله عنه ـ يَقُولُ لَمَّا أَرَادَ النَّبِيُّ صلى الله عليه وسلم أَنْ يَكْتُبَ إِلَى الرُّومِ، قِيلَ لَهُ إِنَّهُمْ لاَ يَقْرَءُونَ كِتَابًا إِلاَّ أَنْ يَكُونَ مَخْتُومًا. فَاتَّخَذَ خَاتَمًا مِنْ فِضَّةٍ، فَكَأَنِّي أَنْظُرُ إِلَى بَيَاضِهِ فِي يَدِهِ، وَنَقَشَ فِيهِ مُحَمَّدٌ رَسُولُ اللَّهِ.
also referenced under: Book 56, Hadith 151 (In-Book) & Hadith 2938 (DarusSalam)