Muwatta Malik, Book 29, Hadith 6 (USC-MSA)

Yahya related to me from Malik that he had heard that Ali ibn Abi Talib used to say that if a man said to his wife, "You are haram for me," it counted as three pronouncements of divorce. Malik said, "That is the best of what I have heard on the subject."

وَحَدَّثَنِي عَنْ مَالِكٍ، أَنَّهُ بَلَغَهُ أَنَّ عَلِيَّ بْنَ أَبِي طَالِبٍ، كَانَ يَقُولُ فِي الرَّجُلِ يَقُولُ لاِمْرَأَتِهِ أَنْتِ عَلَىَّ حَرَامٌ إِنَّهَا ثَلاَثُ تَطْلِيقَاتٍ ‏.‏ قَالَ مَالِكُ وَذَلِكَ أَحْسَنُ مَا سَمِعْتُ فِي ذَلِكَ ‏.‏

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also referenced under: Book 29, Hadith 1158 (In-Book)