Sunan an-Nasa'i, Volume 1, Book 6, Hadith 512 (DarusSalam)

Al-'Ala' narrated to us that he entered upon Anas bin Malik in his house in Al-Basrah, when he had finished Zuhr, and his house was beside the Masjid. "When we entered upon him, he said: 'Have you prayed 'Asr?' We said: 'No, we have just finished Zuhr.' He said: 'Pray 'Asr.' So we got up and prayed, and when we finished he said: 'I heard the Messenger of Allah say: "That is the prayer of the hypocrite: he sits and delays 'Asr prayer until (the sun) is between the horns of the Shaitan, then he gets up and pecks four (Rak'ahs) in which he only remembers Allah a little.'"

أَخْبَرَنَا عَلِيُّ بْنُ حُجْرِ بْنِ إِيَاسِ بْنِ مُقَاتِلِ بْنِ مُشَمْرِجِ بْنِ خَالِدٍ، قَالَ حَدَّثَنَا إِسْمَاعِيلُ، قَالَ حَدَّثَنَا الْعَلاَءُ، أَنَّهُ دَخَلَ عَلَى أَنَسِ بْنِ مَالِكٍ فِي دَارِهِ بِالْبَصْرَةِ حِينَ انْصَرَفَ مِنَ الظُّهْرِ - وَدَارُهُ بِجَنْبِ الْمَسْجِدِ - فَلَمَّا دَخَلْنَا عَلَيْهِ قَالَ أَصَلَّيْتُمُ الْعَصْرَ قُلْنَا لاَ إِنَّمَا انْصَرَفْنَا السَّاعَةَ مِنَ الظُّهْرِ ‏.‏ قَالَ فَصَلُّوا الْعَصْرَ ‏.‏ قَالَ فَقُمْنَا فَصَلَّيْنَا فَلَمَّا انْصَرَفْنَا قَالَ سَمِعْتُ رَسُولَ اللَّهِ صلى الله عليه وسلم يَقُولُ ‏ "‏ تِلْكَ صَلاَةُ الْمُنَافِقِ جَلَسَ يَرْقُبُ صَلاَةَ الْعَصْرِ حَتَّى إِذَا كَانَتْ بَيْنَ قَرْنَىِ الشَّيْطَانِ قَامَ فَنَقَرَ أَرْبَعًا لاَ يَذْكُرُ اللَّهَ عَزَّ وَجَلَّ فِيهَا إِلاَّ قَلِيلاً ‏" ‏ ‏.‏

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also referenced under: Book 6, Hadith 515 (In-Book)