Sunan an-Nasa'i, Hadith 5278 ⓘ
It was narrated that Anas said: "The Messenger of Allah [SAW] wanted to write to the Romans, and they (the Companions) said: 'They do not read any letter unless it has a seal.' So he took a ring of silver and it is as if I can see its whiteness on his hand, and engraved on it (were the words): 'Muhammad Rasul Allah.'"
أَخْبَرَنَا حُمَيْدُ بْنُ مَسْعَدَةَ، عَنْ بِشْرٍ، - وَهُوَ ابْنُ الْمُفَضَّلِ - قَالَ حَدَّثَنَا شُعْبَةُ، عَنْ قَتَادَةَ، عَنْ أَنَسٍ، قَالَ أَرَادَ رَسُولُ اللَّهِ صلى الله عليه وسلم أَنْ يَكْتُبَ إِلَى الرُّومِ فَقَالُوا إِنَّهُمْ لاَ يَقْرَءُونَ كِتَابًا إِلاَّ مَخْتُومًا . فَاتَّخَذَ خَاتَمًا مِنْ فِضَّةٍ كَأَنِّي أَنْظُرُ إِلَى بَيَاضِهِ فِي يَدِهِ وَنُقِشَ فِيهِ مُحَمَّدٌ رَسُولُ اللَّهِ .
also referenced under: Book 48, Hadith 239 (In-Book) & Volume 6, Book 48, Hadith 5280 (DarusSalam)